| Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Ammonium Bifluoride, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc. Our services are 24/7 deliveries, including week-end deliveries, wellsite logistics in ISO tanks, logistics & warehousing across the world, sourcing from overseas, manufacturing overseas, quality control, GHS compliance, etc. |
| Aadhunik Industries and/or associated units are FDA-cGMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We supply very high purity standards as per specifications required. |
---------- 
---------- 
Translate
Ammonium Bifluoride Manufacturers Exporters
SDS, MSDS of Ammonium Bifluoride Manufacturers
Specifications of Ammonium Bifluoride:| PARAMETERS | TYPICAL ANALYSIS |
| NH4HF2, % | 96.0 minimum |
| NH4F, % | 4.0 maximum |
| F % | 65.0 minimum |
| Fe, ppm | 10 maximum |
| SO4, ppm | 100 maximum |
| SiO2, ppm | 100 maximum |
| Cl, ppm | 30 maximum |
| AS, ppm | 10 maximum |
| Pb, ppm | 5.0 maximum |
| Ni, ppm | 10 maximum |
| Cu, ppm | 30 maximum |
| Sb, ppm | 10 maximum |
| H2O, ppm | 1000 maximum |
Ammonium Bifluoride manufacturers exporters at:
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.
e-mail: info@aadhunikindustries.com
Copyright and Usual Disclaimer is Applicable. 6-06-2022
Ammonium Bifluoride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Ammonium hydrogen difluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Molecular Weight: 57.04
Chemical Formula: NH4HF2
Relevant Uses: Fracturing and Industrial use only.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral: Category 3
Skin corrosion/irritation Category 1A, B, C
Serious eye damage/eye irritation Category 1
Specific target organ toxicity, repeated exposure Category 2
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Toxic |
GHS Label Elements |
GHS Label Elements |
Signal Words: Danger
Hazard Statements:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.
Precautionary Statements:
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P273: Avoid release to the environment.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P:273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. P337+P313: If eye irritation persists get medical advice/attention.
Remove contact lenses if present and easy to do – continue rinsing.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403+P404: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T Toxic, Xn Harmful
R20, R25, R41, R48
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.
3. Composition/Information on Ingredients
Ingredient: Ammonium Bifluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Percent: 95 - 100%
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Products of Combustion: Ammonia, Nitrogen oxides, Hydrofluoric acid and fumes.
Fire: Ammonium Bifluoride is not considered to be a fire hazard.
Explosion: Ammonium Bifluoride is not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Ammonium Bifluoride is a poisonous solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.
7. Handling and Storage
Toxic! Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ammonium Bifluoride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist Ammonium Bifluoride and concentrated solutions can corrode steel.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
2.5 mg/m3 USA (OSHA) - Table Z-1 Limits for Air Contaminants
(Vacated) TWA: 2.5 mg/m3 OSHA PEL
TWA 2.5 mg/m3 ACGIH TLV
TWA: 2.5 mg/m3 NIOSH IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Ammonium Bifluoride is white crystals, powder or granules.
Odor: Pungent.
Solubility: It is freely soluble in water.
pH: 3.5.
Density: 1.5 g/mL
Molecular Weight: 57.04
Chemical Formula: NH4HF2
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 240C
Melting Point: 125C
10. Stability and Reactivity
Stability: Ammonium Bifluoride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic hydrogen fluoride fumes when heated to decomposition. It may form Ammonia, Nitrogen oxides and Hydrogen fluoride and Fluorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong acids and bases.
Conditions to Avoid: Incompatibles and direct sunlight and moisture..
11. Toxicological Information
Acute toxicity
Toxic, and may be fatal, if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Cough, Shortness of breath, Headache, Nausea
Toxicity data
ORL-RAT LD50 130 mg kg-1
LD50 Intraperitoneal – rat – 31 mg/kg
LC50 – mouse – 342 mg/kg – 1 hour
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
Toxicity to fish: Not available.
Toxicity to daphnia and other aquatic invertebrates: Not available.
Environmental Toxicity: Not available.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
USA DOT, IMDG & Canada TDG Classification:
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID
IATA/ICAO
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID
15. Regulatory Information
USA:
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazardous Categorization: Acute Health Hazard
California Proposition 65: This product does not contain any Proposition 65 chemicals
Canada WHMIS Hazard Class: D1B Toxic materials, E Corrosive material
Canadian Ingredient Disclosure List: listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
EINECS: EC Number: 215-676-4
European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.
Hazard Symbols: T = Toxic; Xn = Harmful
Risk Phrases: R 25 = Toxic if swallowed. R 20 Harmful by inhalation. R41 Risk of serious damage to eyes. R48 Danger of serious damage to health by prolonged exposure.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Hydraulic Fracturing Chemicals