Sulphamic Acid - Sulfamic Acid MSDS Sheet of Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Sulphamic Acid - Sulfamic Acid, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

Chemical Name: Sulfamic Acid, Crystal Grade or Sulphamic Acid
Synonyms:: Amidosulfonic Acid, Amidosulfuric Acid, Aminosulfonic Acid, Sulfamidic Acid

CORROSIVE. CAUSES SKIN, EYE AND RESPIRATORY TRACT BURNS. HARMFUL IF SWALLOWED OR INHALED.
Sulfamic Acid or Sulphamic Acid is harmful or fatal if swallowed. Corrosive to skin and respiratory tract. Can cause permanent damage to eyes. Fire may produce irritating, corrosive and toxic vapors. Firefighters should use full protective equipment and clothing.

Hazard Statements
Can cause irritation of eyes and skin. May cause respiratory tract irritation, and ulceration of the respiratory tract. Avoid contact with eyes and skin. Avoid breathing dusts. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. Keep from contact with clothing and other combustible materials.

Potential Health Effects:
Eyes: Exposure to particulates or solution of this product may cause redness, pain and blurred vision. Prolonged contact may cause corneal injury.
Skin: Sulfamic Acid can cause irritation of the skin with pain, itching and redness. Overexposures may cause chemical burns resulting in blistering of skin and possible scarring. Repeated skin overexposures can result in dermatitis.
Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with symptoms such as nausea, vomiting, and diarrhea.
Inhalation: Sulfamic Acid inhalation may irritate the nose, throat and respiratory tract. Symptoms include sore throat, coughing and shortness of breath. On overexposure, ulceration and perforation of the nasal septum and upper respiratory tract can occur. Pulmonary edema may occur that could potentially lead to death.
HMIS Ratings: Health Hazard: 3* Fire Hazard: 0 Physical Hazard: 1

Eyes: In case of contact with eyes, rinse immediately with plenty of water for at least 20 minutes. Seek immediate medical attention.
Skin: Remove all contaminated clothing. For skin contact, wash thoroughly with soap and water for at least 20 minutes. Seek immediate medical attention if irritation develops or persists.
Ingestion: Do not induce vomiting. If swallowed, wash out mouth with water provided person is conscious. Never give anything by mouth to a victim who is unconscious or having convulsions. Contact a physician or poison control center immediately.
Inhalation: Remove source of contamination or move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration. Administer oxygen if breathing is difficult. Get immediate medical attention.
Notes to Physician: Provide general supportive measures and treat symptomatically.

Flash Point: Sulfamic Acid is not flammable
Upper Flammable Limit (UEL): 9.3% (v/v) [solution]
Lower Flammable Limit (LEL): 9.3% [solution]
Auto Ignition: Not available
Flammability Classification: Not available
General Fire Hazards: As a solid, Sulfamic Acid or Sulphamic Acid is not combustible, however as a solution, it is corrosive and presents a severe inhalation and contact hazard to firefighters. Aqueous solutions of Sulfamic Acid are highly corrosive, which react violently with bases. When involved in a fire, this material may decompose and produce corrosive and/or toxic gases (i.e. ammonia and sulfur oxides).
Hazardous Combustion Products: Nitrogen oxides, carbon oxides, sulfur oxides, and ammonia.
Extinguishing Media: Dry chemical, foam, carbon dioxide, water fog. Use water to cool fire-exposed containers and to protect personnel.
Fire Fighting Instructions: Firefighters should wear full protective clothing including self-contained breathing apparatus. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
NFPA Ratings: Health: 3 Fire: 0 Reactivity: 0

Containment Procedures: Stop the flow of material, if this can be done without risk. Contain the discharged material. If sweeping of a contaminated area is necessary use a dust suppressant agent, which does not react with product (see Section 10 for incompatibility information).
Clean-Up Procedures: For small releases, clean-up spilled liquid wearing gloves, goggles, face-shield, and suitable body protection. Sweep-up or vacuum spilled solid. Decontaminate the area thoroughly. Neutralize spill residue with hydrated lime (calcium oxide), soda ash or sodium bicarbonate. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable container. Prevent spill from contamination of storm drains, sewers, soil or groundwater.
Evacuation Procedures: Evacuate the area promptly and keep upwind of the spilled material. Isolate the spill area to prevent people from entering. Keep materials which burn away from spilled material. In case of large spills, follow all facility emergency response procedures.
Special Procedures: Remove soiled clothing and launder before reuse. Avoid all skin contact with the spilled Sulfamic Acid or Sulphamic Acid.

Handling Procedures: All employees who handle this material should be trained to handle it safely. Do not breathe dust. Avoid all contact with skin and eyes. Use this product only with adequate ventilation. Wash thoroughly after handling.
Storage Procedures: Keep container of Sulfamic Acid or Sulphamic Acid tightly closed when not in use. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store containers away from incompatible chemicals.
Storage Procedures: Storage areas should be made of corrosion- and fire-resistant materials. Post warning and “NO SMOKING” signs in storage and use areas, as appropriate. Use corrosion-resistant structural materials, lighting, and ventilation systems in the storage area. Floors should be sealed to prevent absorption of this material. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. Empty containers may contain residual particulates; therefore, empty containers should be handled with care. Do not cut, grind, weld, or drill near this container. Never store food, feed, or drinking water in containers which held this product. Keep Sulfamic Acid or Sulphamic Acid away from food, drink and animal feed. Do not store Sulfamic Acid in open or unlabeled containers. Limit quantity of material stored.

Exposure Guidelines
A: General Product Information: Follow the applicable exposure limits.
B: Component Exposure Limits: The exposure limits given are for Particulates Not Otherwise Classified.
OSHA: 15 mg/m3 TWA (Total dust)
5 mg/m3 TWA (Respirable fraction)
DFG MAKs 4 mg/m3 TWA (Inhalable fraction)
1.5 mg/m3 TWA (Respirable fraction)
Engineering Controls: Use mechanical ventilation such as dilution and local exhaust. Use a corrosion-resistant ventilation system and exhaust directly to the outside. Supply ample air replacement. Provide dust collectors with explosion vents.
Personal Protective Equipment:
Eyes/Face: Wear safety glasses with side shields (or goggles) and a face shield, if this material is made into solution.
Respiratory: If respiratory protection is needed, use of a full-face-piece pressure/demand SCBA or a full face-piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA’s Respiratory Protection Standard (1910.134-1998). If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection.
General: Have an eyewash fountain and safety shower available in the work area. Use good hygiene practices when handling this material, including changing and laundering work clothes after use. Discard contaminated shoes and leather goods.

Appearance: Sulfamic Acid or Sulphamic Acid is white crystalline solid
Odor: Odorless
Physical State: Solid
pH: 1.18 (1% solution) at 20 deg C
Vapor Pressure: Not applicable
Vapor Density: Not applicable
Boiling Point: Decomposes @ 408 deg F(209 deg C)
Freezing/Melting Point: 205 deg C (401 deg F)
Solubility (H2O): 14.7% at 0 deg C
Specific Gravity: 2.125 (H2O = 1)
Softening Point: Not available
Decomposition Temp.: 209 deg C (408.2 deg F)
Bulk Density: 2.126 g/ cm3 (68.5 lb/ft3)
Molecular Weight: 97.09
Boiling Point 60% Solution: 107 deg C (224.6 deg F)
Chemical Formula: NH2SO3H

Chemical Stability: Sulfamic Acid or Sulphamic Acid is stable when dry, but slowly hydrolyzes in solution. Sulfamic Acid begins to decompose at 209 deg C (408 deg F). At room temperature, dilute solutions of Sulfamic Acid is stable for many months. At higher temperatures and especially in stronger solutions, hydrolysis of the acid and its ammonium salt occurs, forming ammonium hydrogen sulfate and ammonium sulfate. This reaction occurs much more rapidly as the pH lowers (concentration of the acid increases).
Conditions to Avoid: Avoid dispersion of Sulfamic Acid particulates into air and contact with heat. Avoid the use of non-vented containers if concentrated solutions of the acid are made and heated, as a runaway hydrolysis reaction will occur, generating sufficient steam in the container to cause an explosion.
Incompatibility: Incompatible with chlorine and chlorine compounds, cyanides, sulfides, nitrites, nitrates, carbonates, metal oxides, strong oxidizing agents and strong bases. Chlorination of Sulfamic Acid with acidic ammonium chloride solutions gives the powerfully explosive oil, nitrogen trichloride. Heating mixtures of barium, potassium or sodium amidosulfates or Sulfamic Acid, with sodium or potassium nitrates or nitrites, leads to reactions which may be explosive. Mixing Sulfamic Acid with fuming nitric acid results in violent release of nitrous oxide.
Hazardous Decomposition Nitrogen oxides, carbon oxides, sulfur oxides and ammonia gas. Concentrated solutions, when heated, will release sulfur dioxide, and sulfur trioxide. Aqueous solutions of Sulfamic Acid slowly hydrolyze to form ammonium sulfate and ammonium bisulfate.
Hazardous Polymerization: Will not occur.

Acute and Chronic Toxicity
Sulfamic Acid or Sulphamic Acid is harmful or fatal if swallowed. Product is an eye and skin irritant, and can cause burns. Sulfamic Acid is a respiratory tract irritant, and inhalation may cause nose irritation, sore throat, coughing, and chest tightness and possibly, ulceration and perforation of the nasal septum. Inhalation exposure to high levels could cause pulmonary edema (buildup of fluid in the lungs) which could result in death. Ingestion can result in severe gastric distress with possible circulatory collapse, kidney failure and liver and heart damage.
Chronic: Long term skin overexposure to this product may lead to dermatitis and eczema. Prolonged or repeated eye contact may cause conjunctivitis and possibly corneal abnormalities.

Oral-Rat LD50: 3160 mg/kg ;
Oral-Mouse LD50: 1312 mg/kg ;
Oral-Guinea Pig, adult LD50: 1050 mg/kg;
Carcinogenicity: No information available
Epidemiology: No information available
Neurotoxicity: No information available
Mutagenicity: No information available
Teratogenicity: No information available
Other Toxicological Information: No information available

Ecotoxicity: Harmful to aquatic life in very low concentrations. Sulfamic Acid is toxic to fish and marine organisms when applied to streams, rivers, ponds or lakes.
Environmental Fate: No information available.

USA EPA
As shipped, this product has no EPA waste code. Solutions of this product may be considered D002, corrosivity waste under RCRA. Wastes should be tested to determine applicability. No EPA Waste Numbers are applicable for this product's components.

Disposal Instructions
All wastes must be handled in accordance with local, state and federal regulations.

US DOT Information
UN/NA #: UN 2967
Shipping Name: Sulfamic acid
Hazard Class: 8
Packing Group: III
Required Label(s): Class 8
International Air Transport Association (IATA):
UN/NA #: UN 2967
Proper Shipping Name: Sulphamic acid
Hazard Class: 8
Packing Group: III
Passenger & Cargo Aircraft Packing Instruction: 8
Passenger & Cargo Aircraft Maximum Net Quantity: 25 kg
Limited Quantity Packing Instruction (Passenger & Cargo Aircraft): Y822
Limited Quantity Maximum Net Quantity (Passenger & Cargo Aircraft): 5 kg
Cargo Aircraft Only Packing Instruction: 823
Cargo Aircraft Only Maximum Net Quantity: 100 kg
Special Provisions: None
ERG Code: 8L
International Maritime Organization (I.M.O.)
For shipments via marine vessel transport, the following classification information applies.
UN/NA #: UN 2967
Proper Shipping Name: Sulphamic acid
Hazard Class: 8
Packing Group: III
Special Provisions: None
Limited Quantities: 5 kg
Packing Instructions: P002, LP02
IBC Instructions: IBC08
Special Provisions: B3
EmS: F-A S-B
Stowage and Segregation: Category A

This product does not contain any chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A).
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4):
SARA 302 (EHS TPQ): There are no specific Threshold Planning Quantities for Sulfamic Acid. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20.
C: Sara 311/312 Tier II Hazard Ratings:
Component Sulfamic Acid
CAS # 5329-14-6
Fire Hazard No
Reactivity Hazard No
Pressure Hazard No
Immediate Health Hazard Yes
Chronic Health Hazard Yes

California Proposition 65
Sulfamic Acid is not on the California Proposition 65 chemical lists.

B: Component Analysis - State
The following components appear on one or more of the following state hazardous substance lists:

Component CAS # CA FL MA MN NJ PA
Sulfamic Acid 5329-14-6 No No No No Yes No

Component Analysis - WHMIS IDL
This product is listed under the Canadian Hazardous Products Act Ingredient Disclosure List:

ANSI LABELING (Z129.1): DANGER! MAY BE FATAL IF SWALLOWED. CAUSES SKIN AND EYE BURNS. HARMFUL IF INHALED. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing dusts or particulates. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, face-shields, suitable body protection, and NIOSH/MSHA-approved respiratory protection, as appropriate.

FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get medical attention.

IN CASE OF SPILL: Absorb spill with inert material or neutralizing agent for bases. Place residue in suitable container. Consult Material Safety.

Disclaimer:
*******************************
Our company provides this Sulfamic Acid or Sulphamic Acid MSDS information in good faith but makes no representation as to its comprehensiveness or accuracy. This Sulfamic Acid or Sulphamic Acid MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
*******************************

CAS Number 5329-14-6, Sulphamic Acid - Sulfamic Acid manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.