Citric Acid Solution MSDS Sheet

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Citric Acid Solution, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

MSDS Name: Citric Acid Solution, Anhydrous
Synonyms: 2-Hydroxy-1,2,3-propanetricarboxylic acid Solution

EMERGENCY OVERVIEW
Caution! Citric Acid Solution causes respiratory tract irritation. May cause digestive tract irritation. Moisture sensitive. Causes severe eye irritation. May cause skin sensitization by skin contact. Causes skin irritation.
Target Organs: None.
Potential Health Effects
Eye: Citric Acid Solution causes severe eye irritation and possible injury.
Skin: Citric Acid Solution causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: Citric Acid Solution may cause gastrointestinal irritation with nausea, vomiting and diarrhea. Excessive intake of Citric Acid Solution may cause erosion of the teeth.
Inhalation: Citric Acid Solution causes respiratory tract irritation.
Chronic: Repeated exposure may cause sensitization dermatitis.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.

General Information: Use proper personal protective equipment.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Very fine particles of Citric Acid Solution can cause a fire or explosion. Eliminate all ignition sources. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Spill of Citric Acid Solution may be neutralized with lime. Do not get water inside containers.

Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container of Citric Acid Solution tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep Citric Acid Solution from contact with moist air and steam.
Storage: Store Citric Acid Solution in a tightly closed container. Store away from oxidizers. Store in a cool, dry, well-ventilated area away from incompatible substances. Store Citric Acid Solution protected from moisture.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Citric Acid Solution.

Appearance: Citric Acid Solution is clear to off-white.
Odor: Citric Acid Solution is odorless.
Solubility: ca. 60 g/100 ml @ 20C (Anhydrous)
Density: 1.542
pH: 2.2 (0.1 N sol)
% Volatiles by volume @ 21C (70F): 0
Boiling Point: No information found.
Melting Point: ca. 100C (ca. 212F)
Molecular Weight: 192.13 (Citric Acid, Anhydrous)
Molecular Formula: C6H807 (Citric Acid, Anhydrous)

Chemical Stability: Citric Acid Solution is stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, sulfides (inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), metal nitrates, alkali carbonates, alkalis, potassium tartrate, acetates, bicarbonates.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Oral rat LD50: 3 gm/kg; irritation skin rabbit: 500 mg/24H mild; eye rabbit: 750 ug/24H severe.

--------\Cancer Lists\-----------------------------------------
------------------------ NTP Carcinogen---
Ingredient ------------- Known -- Anticipated -- IARC Category
------------------------ ----- -- ----------- -- -------------
Citric Acid Solution (77-92-9) -- No --No ------- None

Environmental Fate: No information found.
Environmental Toxicity: No information found.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Citric Acid Solution and unused contents in accordance with local requirements.

USA FEDERAL
TSCA
CAS# 77-92-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 77-92-9: acute.
CAS# 77-92-9: 0
CERCLA: Not listed
California 65: This product does not contain any substance(s) which are defined by the state of California to cause cancer, birth defects, or other reproductive effects.

Component Analysis: - State Citric Acid is listed as follows:
NJ4: New Jersey other (included in 5 predominant ingredients >1%);
PA3: Pennsylvania (non-hazardous - present at 3% or greater)
Component CAS # CA FL MA MN NJ PA
Citric Acid 77-92-9 No No No No Yes Yes

Canada
CAS# 77-92-9 is listed on Canada's DSL List. CAS# 77-92-9 is listed on Canada's DSL List.
Citric Acid Solution has a WHMIS classification of D2B.
CAS# 77-92-9 is listed on Canada's Ingredient Disclosure List.
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. "Xi" – Irritant; S25: Avoid contact with eyes.
WHMIS (Canada): CLASS E: Corrosive solid.

Canadian DSL/NDSL:
CAS# 77-92-9 is listed on Canada's DSL List.
Canada Ingredient Disclosure List:
CAS# 77-92-9 is listed on Canada's Ingredient Disclosure List.
DSCL (EEC):
R36/37/38- Irritating to eyes, respiratory system and skin. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39- Wear suitable gloves and eye/face protection.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves (impervious). Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Safety glasses.

Disclaimer:
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Our company provides this Citric Acid Solution MSDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Citric Acid Solution MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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CAS Number 77-92-9, Citric Acid solution manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.