Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide SDS MSDS of Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

Tertiary Butyl Hydroperoxide or TBHP, SDS GHS, Safety Data Sheet
MSDS, Material Safety Data Sheet 10-Oct-21

Product Name & Other Names: Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide.
CAS No.: 75-91-2
EINECS EC No.: 200-915-7
Molecular Formula: C4H10O2 or (CH3)3COOH
Molecular Weight: 90.12
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 3) H226
Organic peroxides (Type F), H242
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Inhalation (Category 3) H331
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1C), H314
Skin sensitization (Category 1), H317
Germ cell mutagenicity (Category 2), H341
Chronic aquatic toxicity (Category 2), H411

Hazard statements:
H226: Flammable liquid and vapor.
H242: Heating may cause a fire.
H302: Harmful if swallowed.
H331: Toxic if inhaled.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H341: Suspected of causing genetic defects.
H411: Toxic to aquatic life with long lasting effects.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder, and Sand for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Product Name & Other Names: Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide.
CAS No.: 75-91-2
EINECS EC No.: 200-915-7
Percentage: Around 70% in water.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to physicians: Treat symptomatically.

Flammability of the Product: Flammable.
Auto-Ignition Temperature: SADT: 88C.
Flash Points: 42C
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire Extinguishing Media: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder and Sand for extinction. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Remove all sources of ignition. Provide proper ventilation. If liquid - absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep solid/powder up the material without causing dust. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water, and disposed of promptly, preferably by incineration.

Precautions for safe handling: Do not ingest. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like heat, strong oxidizing agents, strong reducing agents, strong acids, strong bases, powdered metals, organic materials.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Recommended storage temperature 2C - 8C.

Airborne Exposure Limits: Not Established. TWA: 0.1 ppm Skin ACGIH TLV
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area.

Appearance: Clear colorless liquid.
Odor: Characteristic.
Odor threshold: No data found.
pH: around 5.
Relative density: 0.9 to 0.94
Melting point/freezing point: -3C.
Initial boiling point and boiling range: 89C to 96C.
Flash point: 42C.
Auto-ignition temperature: SADT: 88C.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): Soluble in water.
Viscosity: No data found.
Molecular Formula: C4H10O2 or (CH3)3COOH
Molecular Weight: 90.12

Stability: Stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at intense warming. Violent reactions possible with: Strong acids, alkalis, Reducing agents, metallic salts.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Toxic Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Heat, strong oxidizing agents, strong reducing agents, strong acids, strong bases. Powdered metals, Organic materials.
Conditions to Avoid: Incompatibles, oxidizing agents, strong alkalis, strong acids, heat & light.

Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No data found.
Teratogenicity: No data found.
Reproductive Effects: No data found.
Mutagenicity: No data found.
Neurotoxicity: No data found.

Toxicity to fish: No data found.
Persistence and Degradability: Soluble in water Persistence is unlikely.
Bioaccumulation/ Accumulation: No data found.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No data found.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN3109
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-BUTYL HYDROPEROXIDE)
Hazard Class: 5.2(8); Packing Group: NA.
IMDG/IMO & IATA/ICAO:
UN Number: UN3109
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-BUTYL HYDROPEROXIDE)
Hazard Class: 5.2(8); Packing Group: NA.

USA:
SARA 311/312 Hazards: Fire Hazard, Immediate Health Hazard. See section 2.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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CAS Number 75-91-2, Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.

GHS Label Elements Toxic	GHS Label Elements Flammable	GHS Label Elements Health Hazard
GHS Label Elements Corrosive	GHS Label Elements Marine Pollutant