Sodium Picramate SDS MSDS of Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Sodium Picramate, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide
SDS, Safety Data Sheet, MSDS

Product Name & Other Names: Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.
CAS Number: 831-52-7
EINECS EC Number: 212-603-8
Molecular Formula: C6H4N3O5Na
Molecular Weight: 221.1
Relevant uses and uses advised against (if any): Industrial Manufacturing.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable solids (Category 1), H228
Acute toxicity, oral (Category 4), H302
Acute toxicity, dermal (Category), 4H312
Sensitization, Skin (Category 1), H317
Specific target organ toxicity, repeated exposure (Category 2), H373
Acute toxicity, inhalation (Category 4), H332
Hazardous to the aquatic environment, acute hazard (Category 2), H401

Hazard statements:
H228: Flammable solid.
H302 + H302 + H332: Harmful if swallowed, in contact with skin and if inhaled.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide for extinction.

Classification according to European Directive 67/548/EEC as amended:
Hazard symbols:
Xn Harmful
Xi Irritant.
Risk-phrases:
R10 Flammable
R20 Harmful by inhalation
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R43 May cause sensitization by skin contact.
R48 Danger of serious damage to health by prolonged exposure.

Product Name & Other Names: Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.
CAS Number: 831-52-7
EINECS EC Number: 212-603-8

Eye Contact: Do not allow victim to rub eye (s). Let the eye (s) water naturally for a few minutes. If particle/dust does not dislodge, flush with lukewarm, gently flowing water for 5 minutes or until particle/dust is removed, while holding eyelid (s) open. If irritation persists, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye.
Skin Contact: Remove contaminated clothing, shoes, and leather goods (e.g., watchbands, belts). Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm gently flowing water and non-abrasive soap for 5 minutes. If irritation persists, repeat flushing. Obtain medical advice. Completely decontaminate clothing, shoes and leather goods before reuse or else discard.
Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. Obtain medical advice.
Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 2 – 8 oz. (60 – 240 ml) of water.

Fire and Explosion Hazards: Flammable Solids.
Extinguishing Media: Use means of extinction appropriate for the surrounding fire conditions such as water spray, carbon dioxide, dry chemical, or foam.
Fire Fighting: Apart from oxides of carbon. toxic fumes of nitrogen oxide may result from combustion. As with any fire, fire fighters should be fully trained and wear full protective clothing including an approved, self-contained breathing apparatus which supplies a positive air pressure within a full-face piece mask. Do not use water directly on material. Do not allow water run-off to enter sewers or watercourses. Use water spray to cool unopened containers. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

Procedures for Cleanup: Stop release if possible, to do so safely. Contain spill, isolate hazard area, and deny entry. Sweep up or vacuum. Place contaminated material in suitable, labeled containers for final disposal. Dispose of waste material consistent with the requirements of waste disposal authorities.
Personal Precautions: Gloves and coveralls or other protective clothing are recommended for persons responding to an accidental release. Close-fitting safety goggles may be necessary in some circumstances to prevent eye contact.
Environmental Precautions: This product can pose a threat to the environment. Contamination of soil and water should be prevented. Keep spillage from entering soil, streams, or sewers.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. generating dust and the release of dust into the workplace. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like oxidizing agents.

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible.
Other Control Measures: Maintain good housekeeping in work area. Maintain eye wash fountain and quick-drench facilities in work area.

Appearance: Red-brown solid.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): Soluble in water.
Viscosity: No data found.

Stability and Reactivity: Stable and not considered reactive under normal temperatures and pressures. Hazardous polymerization or runaway reactions will not occur.
Incompatibilities: Oxidizing agents. Avoid excessive heat.
Hazardous Decomposition Products: High temperature operations will generate carbon oxide fume. Under such conditions, nitrogen dioxide will also be generated and can cause respiratory distress.

Acute Toxicity (Oral LD50): > 378 mg/kg Mouse
LC50 Inhalation - Rat - 1 h - > 3,900 mg/m3
Carcinogenicity: Not listed as a human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: No data found.
Mutagenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.

Ecotoxicity: May cause long lasting harmful effects to aquatic life.
Toxicity to fish: No data found.
Persistence and Degradability: Readily biodegradable.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No data found.
Results of PBT and vPvB assessment: No data found.

Do not wash the material down drain. Put uncontaminated material back into the process if possible. Place contaminated material in suitable, labeled containers for disposal.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I
IATA/ICAO:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I
IMDG/IMO:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I

USA:
California Proposition 65: Not listed.
SARA 311/312 Hazards: See section 2.

European Labeling in Accordance with EC Directives:
H228: Flammable solid.
H302 + H302 + H332: Harmful if swallowed, in contact with skin and if inhaled.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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CAS Number 831-52-7, Sodium Picramate manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.