N-Methyl Piperazine SDS MSDS of Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of N-Methyl Piperazine, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

N-methylpiperazine or N-Methyl Piperazine SDS GHS, Safety Data Sheet
MSDS, Material Safety Data Sheet

Product Name & Other Names: N-methylpiperazine or N-Methyl Piperazine.
CAS No.: 109-01-3
EINECS EC No.: 203-639-5
Molecular Formula: C5H12N2
Molecular Weight: 100.16
Relevant uses and uses advised against (if any): Industrial Manufacturing and laboratory use.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 4), H312
Skin corrosion (Category 1C), H314
Acute toxicity, Inhalation (Category 3) H331

Hazard statements:
H226: Flammable liquid and vapor.
H302 + H312: Harmful if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder and Sand for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
C = Corrosive
T = Toxic
Xn = Harmful
F = Flammable:
R-phrases:
R 10 Flammable.
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R23 Toxic by inhalation.
R41 Risk of serious damage to eyes.

Product Name & Other Names: N-methylpiperazine or N-Methyl Piperazine.
CAS No.: 109-01-3
EINECS EC No.: 203-639-5

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to physicians: Product is a corrosive material. Use of gastric lavage or emesis is contra-indicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal oedema may occur. Marked decrease in blood pressure may occur with frothy sputum, and high pulse pressure.

Products of Combustion: Carbon dioxide, Carbon monoxide, Nitrogen oxides, fumes.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder and Sand for extinction. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray or fog is preferred, if water not available use dry chemical, CO2 or regular foam. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc).
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Remove all sources of ignition. Provide proper ventilation.

Precautions for safe handling: No naked lights. No smoking. Use only under a chemical fume hood. Wear personal protective equipment. Use spark-proof tools and explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Keep away from sources of ignition - No smoking. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. If you feel unwell, seek medical attention.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Keep under nitrogen. Flammables area. Corrosives area. Do not store with incompatible materials like acids, acid chlorides, acid anhydrides, strong oxidizing agents.

Airborne Exposure Limits: Not Established. Keep it below 0.2 ppm. Provide adequate ventilation.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible.
Other Control Measures: Maintain good housekeeping in work area. Maintain eye wash fountain and quick-drench facilities in work area.

Appearance: Clear colorless liquid.
Odor: Amine like.
Odor threshold: Not available.
pH: 11 - 12
Relative density: 0.9.
Melting point/freezing point: -6C.
Initial boiling point and boiling range: 138C.
Flash point: 39C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): No data found.
Viscosity: No data found.

Stability: Stable under ordinary conditions of use and storage. Vapour/air-mixtures are explosive at intense warming. Flammable liquid and vapor. May form flammable vapor-air mixture..
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide, Nitrogen oxides & Toxic Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents.
Conditions to Avoid: Incompatibles, moisture, air, heat, flame, sparks & light.

LD50 Oral - Rat - 2.553 mg/kg.
LC50 Inhalation - Mouse - 2 h - 2,7 mg/l.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Teratogenicity: No data found.
Reproductive Effects: No data found
Mutagenicity: No data found.

Toxicity to fish: No data found.
Persistence and Degradability: Soluble in water Persistence is unlikely.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No data found.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN2734
Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (1-Methylpiperazine)
Hazard Class: 8 (3); Packing Group: II.
IATA and IMDG/IMO:
UN Number: UN2734
Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (1-Methylpiperazine)
Hazard Class: 8 (3); Packing Group: II.

USA:
California Proposition 65: Not listed.
SARA 311/312 Hazards: See section 2.

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H302 + H312: Harmful if swallowed or in contact with skin.
H314: Causes severe skin burns and eye damage.
H331: Toxic if inhaled.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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CAS Number 109-01-3, N-Methyl Piperazine manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.