Lithium Hydroxide SDS MSDS of Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Lithium Hydroxide, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

Lithium Hydroxide Monohydrate and Anhydrous SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet

Product Name & Other Names : Lithium Hydroxide Monohydrate and Anhydrous.
CAS No.: 1310-66-3 monohydrate or 1310-65-2 anhydrous
EINECS EC Number: 215-183-4 or 603-454-3
Molecular Weight: 23.95 for anhydrous and 41.96 for Monohydrate
Chemical Formula: LiOH or anhydrous and LiOH-H2O for monohydrate
Relevant uses and uses advised against (if any) : Laboratory chemicals, Manufacture of substances. For Industrial use.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Skin corrosion/irritation Category 1A, B, C, H314

Hazard statements:
H302: Harmful if swallowed
H314: Causes severe skin burns and eye damage

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P390: Absorb spillage to prevent material damage.
P404: Store in a closed container.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
C Corrosive
Xn Harmful
Risk Phrases:
R-22 Harmful if swallowed.
R35 Causes severe burns.
R41 Risk of serious damage to eyes.

Product Name & Other Names: Lithium Hydroxide Monohydrate and Anhydrous.
CAS No.: 1310-66-3 monohydrate or 1310-65-2 anhydrous
EINECS EC Number: 215-183-4 or 603-454-3

Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eye with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to and unconscious person. Loosen tight clothing such as a collar, tie, belt, or waistband. Get medical attention immediately.
Medical Conditions generally Aggravated by Exposure: Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

Flash Point: NA
Fire Extinguishing Media: Adapt extinguishing media to the environment. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special Fire Fighting Procedures: Wear self contained breathing apparatus for firefighting if necessary. Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Unusual Fire and Explosion Hazards: Flammable hydrogen gas may be produced on prolong contact with metals such as aluminum, tin lead and zinc.
Hazardous combustion products: Oxides of Lithium.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Wear suitable protective equipment. Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Small quantities of liquid spill may be neutralize with acid solution. Wash away neutralized product with plentiful water. Contain spilled material. Take up liquid spill into absorbent material, e.g.: dry sand/earth or powdered limestone. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and water, acids, metals. Always add the material to water while stirring and never the reverse.

Components with workplace control parameters: This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Engineering Controls Ventilation required: The material should be handled or transferred in an approved fume hood or with adequate ventilation.
Personal Protection Equipment
Respiratory protection: If workplace exposure limit (s) of product or any component is high, a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirator (negative pressure type) under specified conditions (see your safety equipment supplier).
Skin protection: Impervious, protective clothing. Protective gloves: Nitrile or equivalent.
Eye protection: Safety glasses with side shields must always be worn .
Additional clothing and/or equipment: Eyewash and safety equipment should be readily available. Handle in accordance with good industrial hygiene and safety practice.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards.

Appearance: White Crystalline Powder. Hygroscopic.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.46 for anhydrous and around 1.51 for monohydrate.
Boiling Point: 924C.
Melting Point: 462C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water. Slightly soluble in ethanol.
Viscosity: No data found.

Stability: Stable under ordinary conditions of use and storage. Very hygroscopic. Absorbs atmospheric CO2.
Reactivity: Exothermic reaction with water. Heat of solution is extremely high and with limited amounts of water, violent boiling may occur. Violent exothermic reaction with strong acids. Reacts with some metals to release hydrogen.
Conditions to Avoid: Contact with moisture may generate sufficient heat to ignite surrounding combustible material.
Materials to Avoid (Incompatibility): Water, acids, chlorinated hydrocarbons, oxidizing agents, metals and organic materials, Nitro compounds, Organic materials, Magnesium, Copper, Water, reacts violently with:, Metals, Light metals, Contact with aluminum, tin and zinc liberates hydrogen gas. Contact with nitromethane and other similar nitro compounds causes formation of shock-sensitive salts., vigorous reaction with: Alkali metals, Halogens, Azides, Anhydrides
Hazardous Decomposition Products: None indicated.
Hazardous Polymerization: Will not occur.

The material is corrosive to all tissues. It is a severe eye, skin, and respiratory tract irritant, and can burn any tissue with which it comes in contact. Contact with eye may cause redness, intense pain, and tearing. In severe cases, conjunctival edema and destruction of cornea may occur, which may result in permanent damage to the eye. It is a severe skin irritant and contact with the skin can cause effects ranging from irritation to burns with deep and painful lesions. Burns may not be immediately painful. The onset of pain after contact may take minutes to hours; however, damage begins immediately.
Extremely hazardous in case of eye contact ( corrosive). Causes severe eye burns. Extremely hazardous in case of skin contact (corrosive). Skin contact produces severe burns. Hazardous in case of skin contact (permeator). Extremely hazardous in case of inhalation (lung corrosive). Hazardous in case of inhalation. Extremely hazardous in case of ingestion. May be fatal if swallowed.
Results of component toxicity test performed:
LD50 Oral - Mouse - 363 mg/kg
LD50 Oral - Rat - 210 mg/kg
LC50 Inhalation - Rat - 4 h: > 615 mg/l
Carcinogenicity: This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.

Toxicity to fish: static test LC50 Danio rerio (zebra fish): 62.2 mg/l; 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 Daphnia magna (Water flea): 19.1 mg/l; 48 h.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Expected to be highly toxic to aquatic organisms and ecosystems due to effects on pH. Harmful effect due to pH shift. Discharge into the environment must be avoided.

Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

DOT USA, TDG Canada & ADR/RID Europe:
Proper shipping name: LITHIUM HYDROXIDE
Hazard Class: 8
Packaging group: II
UN Number: UN2680
IATA:
Proper shipping name: LITHIUM HYDROXIDE
Hazard Class: 8
Packaging group: II
UN Number: UN2680
IMDG/IMO:
Proper shipping name: LITHIUM HYDROXIDE
Hazard Class: 8
Packaging group: II
UN Number: UN2680

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed
H314: Causes severe skin burns and eye damage

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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CAS Number 1310-66-3 monohydrate or 1310-65-2 anhydrous, Lithium Hydroxide USP Grade manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.