Heavy Bismuth Subnitrate SDS MSDS Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Heavy Bismuth Subnitrate, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

Heavy Bismuth Subnitrate or Bismuth Nitrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet

Product Name & Other Names: Heavy bismuth subnitrate or Bismuth (III) nitrate basic or Bismuthyl nitrate or Bismuth(III) oxynitrate or Bismuth(III) subnitrate.
CAS No.: 1304-85-4
EINECS EC Number: 215-136-8
Molecular Weight: 1461.99
Chemical Formula: Bi5O(OH)9(NO3)4
Relevant uses and uses advised against (if any): Industrial Manufacturing.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3, H272
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335
Hazardous to the aquatic environment, acute hazard Category 3, H402

Hazard Statements:
H272: May intensify fire; oxidizer.
H315 : Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Dry chemical, carbon dioxide, Halon, water spray, or fog for extinction. If water is used, apply from as far a distance as possible.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
O Oxidizing
Xi Irritant
Risk Phrases:
R8 Contact with combustible material may cause fire.
R36/37/38 Irritating to eyes, respiratory system and skin.
R52 Harmful to aquatic organisms.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Explosion: Some nitrates may explode when shocked, exposed to heat or flame, or by spontaneous chemical reaction. Sealed containers may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media: Dry chemical, carbon dioxide, Halon, water spray, or fog. If water is used, apply from as far a distance as possible. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong reducing agents, alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Keep away from sources of ignition - No smoking.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards.

Appearance: Solid.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 4.93
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: No data found
Viscosity: No data found.

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of bismuth and nitrogen and toxic metal fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

Toxicity to Animals: Not available.
Carcinogenicity: Not listed as a human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: No data found.
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.

Toxicity data: No data found.
Persistence and Degradability: No data found.
Mobility: No data found.
Bioaccumulation/ Accumulation: No data found.
Results of PBT and vPvB assessment: No data found.

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options.

DOT USA, TDG Canada & ADR/RID Europe
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
International (Water, I.M.O. and IMDG)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
International (Air, I.C.A.O. and IATA)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II

USA:
California Prop. 65 Components: Not listed to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H272 = May intensify fire; oxidizer.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
H402 = Harmful to aquatic life.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Heavy Bismuth Subnitrate BP Ph Eur Grade
Ph Eur
4[BiNO3(OH)2],BiO(OH) -- 1462 -- CAS 1304-85-4

DEFINITION
Content: 71.0 per cent to 74.0 per cent of Bi (Ar 209.0) (dried substance).

CHARACTERS
Appearance: White or almost white powder.
Solubility: Practically insoluble in water and in ethanol (96 per cent). It dissolves in mineral acids with decomposition.

IDENTIFICATION
A. Dilute 1 ml of solution S1 (see Tests) to 5 ml with water and add 0.3 ml of potassium iodide solution. A black precipitate is formed which dissolves into an orange solution with the addition of 2 ml of potassium iodide solution.
B. It gives reaction (b) of bismuth.
C. It gives the reaction of nitrates.
D. pH: maximum 2.0 for solution S2 (see Tests).

TESTS
Solution S1: Shake 5.0 g by gently heating in 10 ml of water and add 20 ml of nitric acid. Heat until dissolution, cool and dilute to 100 ml with water.
Solution S2: Place 1.00 g in a 20 ml volumetric flask and add 2.0 ml of lead-free nitric acid. Allow acid attack to take place without heating and if necessary warm slightly at the end to completely dissolve the test sample. Add 10 ml of water, shake and add, in small fractions, 4.5 ml of lead-free ammonia; shake and allow to cool. Dilute to 20.0 ml with water, shake again is required to change the colour of the indicator to pink.
Chlorides: Maximum 200 ppm.
Copper: Maximum 50.0 ppm.
Lead: Maximum 20.0 ppm.
Silver: Maximum 25.0 ppm.
Substances not precipitated by ammonia: Maximum 1.0 per cent.
To 20 ml of solution S1, add concentrated ammonia until an alkaline reaction is produced and filter. Wash the residue with water and evaporate the combined filtrate and washings to dryness on a water-bath. To the residue, add 0.3 ml of dilute sulphuric acid R and ignite.
The residue weighs a maximum of 10 mg.
Loss on drying: Maximum 3.0 per cent, determined on 1.000 g by drying in an oven at 105C.

CAS Number 1304-85-4, Heavy Bismuth Subnitrate USP BP Ph Eur manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.