Fumaric Acid SDS, MSDS Sheet

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Fumaric Acid, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

Synonyms: 2-Butenedioic acid; Boletic acid
CAS No.: 110-17-8
EINICS EC-No.: 203-743-0
Molecular Weight: 116.07
Chemical Formula: HOOCCH=CHCOOH
Recommended usage: Industrial Manufacturing.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Precautionary statements:
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
HMIS (Perceived): Health hazard: 1, Flammability: 1, Physical hazards: 0
NFPA (Perceived): Health hazard: 2, Fire: 1, Reactivity Hazard: 0

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Symbol: Xi Irritant.
Risk Phrases: R36 – Irritating to eyes.

Ingredient: Fumaric Acid
CAS No.: 110-17-8
EINICS EC-No.: 203-743-0
Percent: 100%

Inhalation: If Fumaric Acid is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.

Keep Fumaric Acid in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Fumaric Acid may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Appearance: Fumaric Acid is white to off-white crystals or powder.
Odor: Faint odor.
Solubility: Soluble in water.
Density: 1,63 g/cm3 at 20 °C
pH: Approximately 2, Acidic.
% Volatile by volume @ 21C (70F): 0
Molecular Weight: 116.07
Chemical Formula: HOOCCH=CHCOOH
Melting Point: 298 - 300°C - lit.

Stability: Fumaric Acid is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Excessive heat, Strong oxidizers.
Conditions to Avoid: Heat, dusting and incompatibles.

LD50 Oral - Rat - female: 9.300 mg/kg
LD50 Dermal - Rabbit - female: 20.000 mg/kg
LD50 Intraperitoneal - Mouse: 100 mg/kg
--------\Cancer Lists\-----------------------------------------
--------------------------- NTP Carcinogen---
Ingredient -------------- Known -- Anticipated -- IARC Category
--------------------------- --------- -- --------------- -- -------------
Fumaric Acid (110-16-7) -- No ----- No ------- -- None

Toxicity to fish daphnia and bacteria:
Toxicity to fish mortality: Danio rerio (zebra fish) - 245 mg/l - 48 h
Toxicity to fish semi-static test LC50: Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates Immobilization EC50: Daphnia magna (Water flea) - 212 mg/l - 48 h
Toxicity to algae Growth inhibition EC50: Pseudokirchneriella subcapitata - > 100 mg/l - 72 h
Toxicity to bacteria Respiration inhibition EC50: activated sludge - > 300 mg/l - 3 h
Bioaccumulative potential: No data available
Mobility in soil: No data available
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Fumaric Acid in accordance with legal requirements.

DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated

USA Regulations:
Comprehensive Environmental Response and Liability Act (CERCLA): This material is not subject to any special reporting under the requirements of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA).
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
The reportable quantity (RQ) for this material is 5000 pounds. If appropriate, immediately report to the National Response Center (800/424-8802) as required by U.S.Federal Law. Also contact appropriate state and local regulatory agencies.
Toxic Substance Control Act (TSCA): All components of this product are listed on the TSCA inventory list.
SARA Section 311/312 (40 CFR 370) Hazard Categories: Acute Health Hazard, Chronic Health Hazard.
SARA Section 313 (40 CFR 372) Hazard Categories: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA.
Clean Air Act: None of the chemicals in this product are listed as Hazardous Substances under the CCA.
California Prop 65: This product contains no chemical known by the State of California to cause cancer, birth defects or other reproductive harm.

EINICS EC-No.: 203-743-0
Label elements according to Directive 67/548/EEC
Symbol: Xi
Risk Phrases: R36 – Irritating to eyes.
Safety Phrases:
S16 - Keep away from sources of ignition - No smoking.
S3 - Keep in a cool place.
S9 - Keep container in a well-ventilated place.
S13 - Keep away from food, drink and animal feeding stuffs
S24 - Avoid contact with skin.
S25 - Avoid contact with eyes.
S36 - Wear suitable protective clothing.
S37 - Wear suitable gloves
S29 - Do not empty into drains.
S45 - In case of accident or if you feel unwell, seek medical advice immediately.
S56 - Dispose of this material and its container to hazardous or special waste collection point.

Disclaimer:
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Our company provides this Fumaric Acid SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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CAS Number 110-17-8, Fumaric Acid manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.