Glacial Acetic Acid SDS MSDS Sheet of Manufacturers Exporters

Aadhunik Industries is a manufacturing group company. Aadhunik Industries is pioneer manufacturers of Glacial Acetic Acid, Specialty Chemicals, Pharmaceutical Excipients, Food Fragrance & Flavor chemicals in India. It has toll manufacturers and representatives in UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan, Russia etc.

Aadhunik Industries and/or associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified. We offer crystals granules in precise micron or mesh size as per buyers needs. We offer very high purity standards as per specifications required.

MSDS Name: Acetic Acid
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Recommended usage: Industrial Manufacturing.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids (Category 3) H227
Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402

Labeling according to GHS & Regulation (EC) No 1272/2008

Hazard statements:
H227: Combustible liquid.
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.

Precautionary statements:
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313: If eye irritation persists: Get medical advice/ attention.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P273: Avoid release to the environment.
P501: Dispose of contents/container to comply with local, state and federal regulations.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: 40C 104F
Auto Ignition Temperature: 463C 865F
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.

Spills/Leaks: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Contain the spill with sand or other inert absorbent material, neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal.

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container of Acetic acid tightly closed. Avoid ingestion and inhalation. Do not allow contact with heat. Do not breathe vapors or spray mist.
Storage: Store Acetic acid in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store Acetic acid protected from heat and flames.

Airborne Exposure Limits: Airborne Exposure Limits:
OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA).
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL).
NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Acetic acid.

Appearance: Clear Liquid
Odor: Vinegar odor
Solubility: Soluble in water
Specific Gravity: 1.049
pH: 2 for 1% solution, 2.4 (1.0M solution)
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 118C
Melting Point: 16.6C
Molecular Formula: C2H4O2
Molecular Weight: 60.05

Chemical Stability: Acetic acid is stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to heat, spark, moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Acute oral toxicity (LD50): 3310 mg/kg [Rat].
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit].
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse].
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours
The material is not reported as a carcinogen.

Environmental Fate: The material will readily biodegrade.
Environmental Toxicity: (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia].

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Acetic acid and unused contents in accordance with local requirements.

DOT (US) and ADR/RID
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs
Marine pollutant: No
IATA
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial

USA:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA Section 302 (RQ): CAS# 64-19-7: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: CAS# 64-19-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Canada:
CAS# 64-19-7 is listed on Canada's DSL List.
This product has a WHMIS classification of B3, E.
CAS# 64-19-7 is listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.

CAS Number 64-19-7, Glacial Acetic Acid BP and FCC Food Grade manufacturers suppliers exporters at:

manufacturer supplier exporter
Aadhunik Industries
Ankleshwar Gujarat & Mumbai, India
TEL: (OFFICE) 91-22-23774610, 23723564.